BaO(X 1Σ+) vibrational relaxation

✍ Scribed by S.A. Edelstein; B.E. Perry; D.J. Eckstrom; T.F. Gallagher

• Publisher: Elsevier Science
• Year: 1977
• Tongue: English
• Weight: 334 KB
• Volume: 50
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(77)80179-6

✦ Synopsis

Vlbrationdlly cxcitcd l3aO(X "3 was produced by rmctuig R.! storm with 02 under "'jet flow" conditions 111 which the convective flow vcloclty was Iil;gC compared wtth the chffucion velocities so that the rclaudtion could bc qmti,llly ICsolved. The vlbratlonal lcvcl populatums wcrc dctcrmincd by laser-Induced fluorc\ccncc mcmmmmt~. 13~ usmg motlclmg calculations to fit the spatial v:matmn of the apparent vibratmnal tcrnperaturc, WC obtamcd :I vlbratlonal rcla\atlon rate for RaO(X ' 23, u = 1 -* u = 0. hy Ar, of 9 X lO-'3 m~3/niolcculc s.