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Band strengths of fundamentals and overtones of the CF and CH chromophores in CHD2F

✍ Scribed by C. Kormann; M. Lewerenz; M. Quack

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
408 KB
Volume
149
Category
Article
ISSN
0009-2614

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✦ Synopsis

Large quantities of CHDIF have been synthesized by a newly developed method. A complete survey of the fundamental and high overtone spectrum of CHD,F covering the frequency range from 700 to 14000 cm-' has been measured in part at close to Doppler-limited resolution. The overtone spectrum is found to be dominated by muhiple Fermi resonances between CH-stretching and -bending states. The integrated band strengths of the fundamentals and overtones of the CF and CH chromophores have been measured and are interpreted using group additivity models and the Mecke dipole function.

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