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Baeyer—Villiger Oxidation of 4-Methylated 3-Keto Steroids and the Facile Pyrolysis of 4,4-Dimethyl 3,4-Seco Lactones

✍ Scribed by Rosenthal, David; Niedermeyer, Alfred O.; Fried, Josef


Book ID
126830327
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
815 KB
Volume
30
Category
Article
ISSN
0022-3263

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THE ground state oouformations of the steroid ring systems are in general securely looked in potential wells, can vary but little, and are for the most part well understood. In a 4,4-dimethyl-3-keto-5gC-steroid (I) however, there is reason to question whether or not ring A will be in the standard ch