From a comparison with the spectrum of NiF, a low-lying 2 ⌺ ϩ state is expected to lie in the first 2000 cm Ϫ1 above the ground X 2 ⌸ 3/ 2 state of NiCl. The identification of this 2 ⌺ ϩ (v ϭ 0) state (at 1768 cm Ϫ1 ) has been carried out through the analysis of two electronic transitions 2 ⌸ 3/2 -2
BaCl Laser-Induced Fluorescence for Seven Low-Lying Electronic States
✍ Scribed by C. Amiot; M. Hafid; J. Vergès
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 495 KB
- Volume
- 180
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
Laser-induced fluorescence was observed in the BaCl molecule after excitation by all the Ar / and Kr / ion laser radiations. Several lines of a monomode titanium:sapphire laser have also been used to excite the near-infrared fluorescence. The spectra were recorded by high resolution Fourier transform spectroscopy. The following electronic transitions were rotationally analyzed: A
📜 SIMILAR VOLUMES
Six new electronic transitions of NiCl, recorded by high-resolution Fourier transform spectroscopy, have been studied. The identification of the states involved in these transitions has been made possible by dispersing laser-induced fluorescence at low resolution. Comparison of the results obtained