The solution of the Schrodinger equation for the d-dimensional hydrogen atom in a d-dependent potential defined by Gauss' law has been studied by the shifted l/d method and the 6 expansion. These methods provide analytical formulas for the eigenvalues and eigenfunctions which have been tested agains
Back-of-envelope derivation of the analytical formulas of the atomic wave functions of a D-dimensional atom
✍ Scribed by Haruo Hosoya
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 155 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
✦ Synopsis
A simple algebraic manipulation is presented for obtaining the analytical rectangular coordinate expressions of the atomic orbital wave functions with angular quantum number l of a D-dimensional atom, where no hyperspherical harmonics or any differential calculus is involved. A general expression of the D-dimensional f-orbitals is given which supplements the previously obtained result of D-dimensional d-orbitals.
📜 SIMILAR VOLUMES
## Abstract A recent method proposed to compute two‐electron integrals over arbitrary regions of space [Martín Pendás, A. et al., J Chem Phys 2004, 120, 4581] is extended to deal with correlated wave functions. To that end, we use a monadic factorization of the second‐order reduced density matrix o
The lowest energy equilibrium structures for Lennard -Jones alloy clusters are obtained by means of simulated annealing techniques within the Langevin molecular dynamics formalism. By adjusting the sizes of and the interaction between like and unlike species in the potential energy functional form,
## Abstract In this paper we work in separated locally convex spaces where we give equivalent statements for the formulae of the conjugate function of the sum of a convex lower‐semicontinuous function and the precomposition of another convex lower‐semicontinuous function which is also __K__ ‐increa
The approximation of the Voigt line shape by the linear summation of Lorentzian and Gaussian line shapes of equal width is well documented and has proved to be a useful function for modeling in vivo 1 H NMR spectra. We show that the error in determining peak areas is less than 0.72% over a range of