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Ba2(RE)Cu3O7−δ(RE=La, Pr, Nd, Sm, Gd): Crystal growth, structure and magnetic properties

✍ Scribed by E. Moran; U. Amador; M. Barahona; R. Saez-Puche; M.A. Alario-Franco; A. Vegas; A. Fuertes; J.M. Gomez de Salazar

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 560 KB
Volume: 32-33
Category: Article
ISSN: 0167-2738
DOI: 10.1016/0167-2738(89)90411-6

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The ternary copper indides RE 2 CuIn 3 RECu 0.5 In 1.5 (RE ¼ Ce, Pr, Nd, Sm and Gd) were synthesized from the elements in sealed tantalum tubes in an induction furnace. They crystallize with the CaIn 2 -type structure, space group P6 3 /mmc, with a statistical occupancy of copper and indium on the t

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Preparation, Crystal Structures, and Properties of Rhenates with Multiple Re–Re Bonds: Ln2ReO5 (Ln=Sm, Eu, Gd), Ln3Re2O9 (Ln=Pr, Nd, Sm), and Ln4Re6O19 (Ln=La–Nd)

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Most of the title compounds were prepared by reaction of the rare-earth metaperrhenates Ln(ReO 4 ) 3 with the rare-earth metals in sealed silica tubes. Nd 4 Re 6 O 19 was obtained by reaction of the intermetallic compound NdRe 2 with the metaperrhenate Nd(ReO 4 ) 3 . The compounds Ln 2 ReO 5 crystal