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B-podand complexes with sodium ions: the reaction heats and PM5 semiempirical calculation

✍ Scribed by Bogusława Łęska; Radosław Pankiewicz; Oksana Nevecheriya; Volodimir I. Rybachenko; Grzegorz Schroeder; Bogumił Brzezinski

Book ID
104058661
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
548 KB
Volume
840
Category
Article
ISSN
0022-2860

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✍ Bogusława Łęska; Piotr Przybylski; Joanna Wyrwał; Bogumił Brzezinski; Grzegorz S 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 333 KB

Silicon podands (1-10) were synthesised and their complexation reaction of Na C cations were studied by calorimetric and PM5 theoretical methods. Both methods provide evidence for formation of the respective complexes with Na C cations of different stoichiometry. In most cases, only formation of the