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B-Alkyl Suzuki–Miyaura cross-coupling of tri-n-alkylboranes with arylbromides bearing acidic functions under mild non-aqueous conditions

✍ Scribed by Hui-Xia Sun; Zhi-Hua Sun; Bing Wang

Book ID
104096217
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
1017 KB
Volume
50
Category
Article
ISSN
0040-4039

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✦ Synopsis

An efficient and chemoselective Pd-catalyzed B-alkyl Suzuki-Miyaura cross-coupling of tri-n-alkylboranes with arylbromides possessing acidic functions is described. This protocol features the relatively weak base Cs 2 CO 3 and mild non-aqueous conditions. Aldehydes, ketones, nitriles, and chloro substitution are all tolerated.

📜 SIMILAR VOLUMES

ChemInform Abstract: Direct B-Alkyl Suzu
ChemInform Abstract: Direct B-Alkyl Suzuki—Miyaura Cross-Coupling of Trialkylboranes with Aryl Bromides in the Presence of Unmasked Acidic or Basic Functions and Base-Labile Protections under Mild Non-Aqueous Conditions.
✍ Bing Wang; Hui-Xia Sun; Zhi-Hua Sun; Guo-Qiang Lin 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 41 KB 👁 2 views

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