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Azo dye oxidation with hydrogen peroxide catalysed by manganese 1,4,7-triazacyclononane complexes in aqueous solution
β Scribed by Gilbert, Bruce C.; Lindsay Smith, John R.; Newton, Maurice S.; Oakes, John; Pons i Prats, Roger
- Book ID
- 115513347
- Publisher
- Royal Society of Chemistry
- Year
- 2003
- Tongue
- English
- Weight
- 274 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1477-0520
- DOI
- 10.1039/b301026k
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π SIMILAR VOLUMES
The dinuclear manganese complex [LMnrV(O)3MnVeL](PF6)2, where L is 1,4,7-trimethyl-l,4,7-triazacyclononane, catalyses the oxygenation ofalkanes by peroxyacetic acid or by H202 in the presence of acetic acid to give alkanols, alkanones and alkyl hydroperoxides. The reactions can give large turnovers
The reaction of indole-3-acetic acid (IAA) with hydrogen peroxide catalysed by . 5,10,15,20-tetrakis(2',6'-dichloro-3'sulfonatophenyl)porphyrinatoiron(III)hydrate [Cl,TPPS,Fe(IIIWOH,),l g' tves indole-3-carbinol (IC) and indole-3-carboxaldehyde (IA) in aqueous buffer solution. The oxidation of IAA w