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Aziridine-2-carboxylic acid mediated asymmetric synthesis of D-erythro- and L-threo-sphingosine from a common precursor

โœ Scribed by Franklin A. Davis; G.Venkat Reddy


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
189 KB
Volume
37
Category
Article
ISSN
0040-4039

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Asymmetric synthesis of carbohydrates: S
โœ Michael E. Jung; John M. Gardiner ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 394 KB

Ahstractz The acctyknii alcohol, 3, readily prepared in two steps from propargyl bromide. 1. is converted to ethyl 2dcoxy-D-xy1ofuTan0side. l3, and to the unnamml L-cnantiomer. 12, in 5 steps and 50% overall yield, utilizing asymmetrk dihydroxylation (AD) of alkcne 7 for intro&&m df chMity. A simila