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Aza-Diels–Alder reactions and synthetic applications of thio-substituted 1,3-dienes with arylsulfonyl isocyanates

✍ Scribed by Shang-Shing P. Chou; Chia-Cheng Hung


Book ID
104210998
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
62 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis


The first aza-Diels-Alder reactions of arylsulfonyl isocyanates with thio-substituted 1,3-dienes via the 3-sulfolene precursors 1 gave the cyclized products 3 with complete control of regio-and chemoselectivity. The cyclized products 3a and 4 underwent further interesting reactions with nucleophiles and bases to give useful heterocyclic compounds.


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ChemInform Abstract: Aza Diels—Alder Rea
✍ Shang-Shing P. Chou; Chia-Cheng Hung 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 35 KB 👁 2 views

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