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✦ LIBER ✦
Aza-Diels–Alder reactions and synthetic applications of thio-substituted 1,3-dienes with arylsulfonyl isocyanates
✍ Scribed by Shang-Shing P. Chou; Chia-Cheng Hung
- Book ID
- 104210998
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 62 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The first aza-Diels-Alder reactions of arylsulfonyl isocyanates with thio-substituted 1,3-dienes via the 3-sulfolene precursors 1 gave the cyclized products 3 with complete control of regio-and chemoselectivity. The cyclized products 3a and 4 underwent further interesting reactions with nucleophiles and bases to give useful heterocyclic compounds.
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## Abstract For Abstract see ChemInform Abstract in Full Text.
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## Abstract For Abstract see ChemInform Abstract in Full Text.