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Axially Dissymmetric diphosphines in the Biphenyl Series: Crystal structures of three new group-VIII metal complexes of (6,6′-dimethyl-1,1′-biphenyl-2,2′-diyl)bis(diphenylphosphine) ( = biphemp)

✍ Scribed by Andreas Knierzinger; Peter Schönholzer


Publisher
John Wiley and Sons
Year
1992
Tongue
German
Weight
604 KB
Volume
75
Category
Article
ISSN
0018-019X

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✦ Synopsis


Dedicated to Prof. Erich Ziegler on the occasion of his 80th birthday (20.111.92) ~~ ~ -(6,6'-Dimethyl-I , l'-hiphenyl-2,2'-diyl)bis(diphenylphosphine) ( = biphemp) reacts with allylmetal halides to yield complexes 1-3 which were transformed into the corresponding perchlorates 4-6. The molecular structures of 4-6 were determined by X-ray analyses.