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Axially chiral 1,1′-binaphthyls with non-identical groups in 2,2′-positions. Synthesis of the enantiomerically pure 2-hydroxy-2′-thiol and substituted 2-amino-2′-thiols

✍ Scribed by Martin Smrčina; Štěpán Vyskočil; Jana Polívková; Jana Poláková; Jan Sejbal; Vladimír Hanus; Miroslav Polášek; Hugh Verrier; Pavel Kočovský

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 708 KB
Volume: 8
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(96)00539-3

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✦ Synopsis

Enantiomerically pure hydroxy thiol (S)-(+)-6, amino thiol (S)-(+)-12, and N,N-dimethylamino thiol (S)-(-)-16 have been synthesized from BINOL (S)-(-)-1 and the amino alcohol (S)-(-)-7, respectively, via the Newman-Kwart rearrangement

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