Measurement of the lattice parameters, vol./atom, and the axial ratio are reported in ternary h.c.p. alloys of the system Ag-Au-Sn, along three lines of constant electron concentration e/a = 1.366, 1.411 and 1.456 respectively. All trends show departures from a possible linear behavior between the
Axial ratio changes in ternary f.c.t. phase alloys of the In-Ga-Tl system
โ Scribed by Y Matsuo; M Kogachi
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 578 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0001-6160
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โฆ Synopsis
The lattice parameters and the axial ratio of disordered f.c.t. In-rich alloys in the ternary system of In-Ga-Tl are measured by the X-ray powder method. The results show that the axial ratio remains constant with increasing Ga content along lines of constant Tl concentration, while it decreases appreciably with increasing Tl content along lines of constant Ga concentration. These trends are qualitatively interpreted in terms of the relation of the first few reciprocal lattice vectors to the first zero position in the mean pseudopotential of the alloy (the "p,,-effect"). VARIATIONS DU RAPPORT DES AXES DANS LES ALLIAGES DE LA PHASE TERNAIRE T.F.C. DU SYSTEME In-Ga-Tl Les parametres du reseau et le rapport axial des alliages desordonnes tetragoneux L faces cent&es riches en In du systeme ternaire In-Ga-TI ont et& mesures aux rayons X par la methode des poudres. Les resultats montrent que le rapport des axes reste constant quand la concentration de Ga augmente a concentration de Tl constante, alors qu'elle diminue de faqon appreciable quand la concentration de TI augmente a concentration de Ga constante. Ces resultats sont interpret& qualitativement it l'aide de la relation entre les premiers vecteurs du reseau reciproque It la premiere position zero dans le pseudopotentiel moyen de l'alliage ("effet q,,"). ANDERUNGEN IM ACHSENVERHALTNIS TERNARER f.c.t. LEGIERUNGEN DES SYSTEMS In-Ga-Tl Die Gitterparameter und das Achsenverhaltnis ungeordneter, flachenzentriert-tetragonaler In-reicher Legierungen des terniiren Systems In-Ga-Tl wurden mit der Debye-Scherrer-Methode gemessen. Die Ergebnisse zeigen, da9 das Achsenverhaltnis mit zunehmendem Ga-Gehalt auf Linien konstanter Tl-Konzentration konstant bleibt, wiihrend es mit zunehmendem Tl-Gehalt auf Linien konstanter Ga-Konzentration betrachtlich abnimmt.
Dieses Verhalten wird qualitativ erklart anhand des Zusammenhangs zwisohen den ersten reziproken Gittervektoren und der ersten Null-Lage des mittleren Pseudopotentials der Legierung ("9,-Effekt").
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