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Axial labilization by macrocyclic ligands. 2. Further kinetics studies of axial substitution in iron(II) complexes of tetrasubstituted bis(.alpha.-diimine) macrocyclic ligands

โœ Scribed by Kildahl, Nicholas K.; Lewis, Thomas J.; Antonopoulos, George.


Book ID
126910143
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
354 KB
Volume
20
Category
Article
ISSN
0020-1669

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Kinetics and mechanisms of substitution
โœ Henrique E. Tomam; Fabio S. Nunes ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 374 KB ๐Ÿ‘ 1 views

The complex [Fe(imox) (Nmim)~], where imox is a planar bis(iminooxime) macrocyclic ligand and Nmim = N-methyl imidazole, undergoes substitution reactions in the presence of 2,2'bipyridine (bipy), leading to a series of intermediate mixed complexes. The forward and reverse rate constants for the subs