Autoxidation of phenols catalyzed by copper(II)-ethylenediamine complexes: the reaction mechanism
โ Scribed by Kushioka, Keiko
- Book ID
- 126787355
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 455 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
In the preceding communication (l), we have reported that primary and secondary amines react with isocyanide in the presence of copper compound as the catalyst to produce amidines in almost quantitative yields. ## N-R " In view of the fact that carbon monoxide is isoelectronic with isocyanide (2)
Substitution reaction with ethylenediamine of coordinated glycinate ligand in bis(ethy1enediamine)glycinatocobalt(II1) complex has been studied in the presence of photo-excited tris(2,2'-bipyridine)ruthenium(II) complex in alkaline aqueous solution (buffered around pH 12) containing 1 . 0 ~ chloride
The mechanism of the a&oxidation of ferrocytochrome c catalysed by some copper complexes has been established. In most cases the rate determining step was found to be the one electron oxidation of the cytochrome by the copper(H) species, which was followed by the rapid reoxidation of the resulting C