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Automerization of Naphthalene in the Presence of Aluminum Chloride

โœ Scribed by Balaban, Alexandru T.; Farcasiu, Dan.

Book ID
127276258
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
367 KB
Volume
89
Category
Article
ISSN
0002-7863

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On the mechanism of the thermal naphthal
On the mechanism of the thermal naphthalene automerization, a comment
โœ Ulrich Burger; Jiri Mareda ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 183 KB

The title reaction is suggested to proceed by a reversible valence isomerization via a laterally bridge benzvalene (2). No analogous behaviour is expected for pyrene. ## cc-13C-naphthalene (1') is known to rearrange thermally into 8-13C-naphthalene (1") following a rate law in accordance with an