Automerization of naphthalene - a correction
✍ Scribed by A.T. Balaban; D. Fa˛rcasiu; V.A. Koptyug; I.S. Isaev; M.I. Gorfinkel; A.I. Rezvukhin
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 125 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Previous communications 3 described the degenerate isomerization (automerization) of naphthalene-l-14C under the influence of aluminium chlOride; degradation of naphthalene vi_..%a 1-nitro-and 1-amino-naphthalene %o phthalic acid and hence by a Schmidt reaction to carbon dioxide and anthranilic acid indicated (for the naphthalene treated with water-promoted aluminium chloride in benzene at 60 ° for 2 hrs) scrambling of the label to all ten carbon atoms in naphthalene.
📜 SIMILAR VOLUMES
The title reaction is suggested to proceed by a reversible valence isomerization via a laterally bridge benzvalene (2). No analogous behaviour is expected for pyrene. ## cc-13C-naphthalene (1') is known to rearrange thermally into 8-13C-naphthalene (1") following a rate law in accordance with an
## Abstract The potential energy surfaces of the naphthalene dimer and benzene–naphthalene complexes are investigated using the recently developed DFT/CCSD(T) correction scheme [__J. Chem. Phys.__ **2008**, __128__, 114 102]. One and three minima are located on the PES of the benzene–naphthalene an
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## Abstract The thermal isomerization of [1,4‐D~2~]‐ (3a) and [1,2‐^13^C~2~]benzene (1a) has been studied in excess hydrogen at 750–850°C with contact time less than 1.2 s and very low partial pressure in a quartz flow system. In both cases, the main isomerization products are the corresponding __m