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Automatic continuous-flow determination of paraquat at the subnanogram per millilitre level

✍ Scribed by Manuel Agudo; Angel Ríos; Miguel Valcárcel


Book ID
102982250
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
534 KB
Volume
281
Category
Article
ISSN
0003-2670

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✦ Synopsis


A flow-through spectrophotometric sensor for the determination of paraquat at the nanogram per mililiitre level based on integration of preconcentration, reaction and detection in the flow-cell is proposed. The determination range achieved depends on the sample volume used. Thus, 250 ml of sample provides detection and determination limits of 0.11 and 0.44 ng ml-' paraquat, respectively. The relative standard deviation was k7.91 for 1.0 ng ml-' paraquat. The potential interference of other pesticides was studied, and the method was used to analyse water samples and study the adsorption of paraquat in different types of soils.


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✍ Tomas Pérez-Ruiz; Carmen Martinez-Lozano; Virginia Tomás 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 659 KB

The catalytic effect of mtnte on the oxldatlon of phenosafranme by bromate m acldlc medmm was studled by usmg the decrease m fluorescence mtenslty of phenosafranme This kmetlc-spectmfluonmetrlc method for mtnte IS linear over the range 0 9-13 8 ng ml-' with a relatwe standard devlatlon of about 15%