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Automated Peak Integration in Multidimensional NMR Spectra by an Optimized Iterative Segmentation Procedure

✍ Scribed by M. Geyer; K.P. Neidig; H.R. Kalbitzer


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
651 KB
Volume
109
Category
Article
ISSN
1064-1866

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✦ Synopsis


A generally applicable method for an automated integration of (n)-dimensional resonance peaks ((n \geqslant 2)) is presented. It is based on an optimized iterative segmentation method combined with a region-growing algorithm and it is independent of the experimental lineshape. The procedure is computationally very efficient and has actually been implemented for two-, three-, and four-dimensional NMR spectra. For isolated peaks, the accuracy of the method is limited only by digital resolution and signal-to-noise ratio. Even for strongly overlapping peaks, the individual volumes can be determined with high accuracy, which is sufficient for all practical applications. e 1995 Academic Press, Inc.