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Automated Parallel Synthesis of MADIX (Co)Polymers

✍ Scribed by Pascal Chapon; Catherine Mignaud; Gilda Lizarraga; Mathias Destarac


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
104 KB
Volume
24
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

An automated parallel synthetic approach has been developed for synthesizing polymer libraries by the Macromolecular Design via the Interchange of Xanthates (MADIX) process. The experimental set‐up, parallel polymerizations, characterization, and reproducibility tests are detailed. Examples of acrylic diblock copolymers synthesized in this way are given.

Automated MADIX polymerizations of BA in the presence of a X~1~‐capped PEA.

magnified imageAutomated MADIX polymerizations of BA in the presence of a X~1~‐capped PEA.


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