A new instrument system has been developed that automatically carries out solvent and thermal denaturations of proteins using fluorescence as a probe of structure. This instrument also automatically performs \(\mathrm{pH}\) titrations and can make kinetic measurements on the time scale of seconds. T
Automated instrumentation for determination of stability constants from solubility
β Scribed by Olin, Aake.; Wikmark, Gunnar.
- Book ID
- 126032649
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 524 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0003-2700
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π SIMILAR VOLUMES
Numerical values of the stability constants for several zinc-pyrophosphate complexes were determined at 25Β°C and 0.20 M ionic strength using a potentiometric titration method. Values of 7.36, 4.49, and 5.63 were found for log K,,,,, 1% &nm, and log K,,,,,,. These constants govern the formation of th
Equilibrium solubility and pH measurements can be used to determine macrodissociation constants of weak acids and bases of some highly insoluble substances. Equations are derived extending solubility, pH, and pKa (macroscopic) relationships to polyprotic, amphoteric substances. A general method for