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[Au(nBuPPh2){(Ph2PS)3C}].CH3CN: an irregular three-coordinate AuI complex

✍ Scribed by Staples, R. J. ;Wang, S. ;Fackler Jnr, J. P. ;Grim, S. O. ;de Laubenfels, E.


Book ID
114510993
Publisher
International Union of Crystallography
Year
1994
Tongue
English
Weight
350 KB
Volume
50
Category
Article
ISSN
0108-2701

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## Abstract Treatment of the polyfunctional ylide Ph~3~P=C(H)C(O)CH~2~COOEt (1) with the solvated complexes [M(C^∧^X)(THF)~2~]ClO~4~ gave the __O__,__O′__ derivatives [M(C^∧^X)(Ph~3~PCH~2~C(__O__)=C(H)−C(=__O__)OEt‐κ‐__O__,__O′__]ClO~4~ [M(C^∧^X) = Pd(C~6~H~4~CH~2~NMe~2~) (2), Pd(CH~2~C~9~H~6~N) (3