✦ LIBER ✦

Augmented BACK equation of state II: Polar fluid mixtures

✍ Scribed by M. J. Lee; K. C. Chao

Publisher: American Institute of Chemical Engineers
Year: 1988
Tongue: English
Weight: 540 KB
Volume: 34
Category: Article
ISSN: 0001-1541
DOI: 10.1002/aic.690341103

No coin nor oath required. For personal study only.

✦ Synopsis

The augmented BACK equation of state for polar fluids is extended to mixtures by introducing mixing rules separately for the nonpolar and polar interactions. Fluid phase equilibria are calculated for polar + nonpolar, and polar + polar mixtures including mixtures of hydrogen-bonding substances. Enthalpy calculations are illustrated with enthalpy of H, S + N, and heats of mixing of steam mixtures, and carbon dioxide mixtures.

Cross interaction coefficients are adjusted for the correlation of data on binary mixtures. Both phase equilibrium and enthalpy data are correlated at the same time with two such coefficients for each binary. The cross interaction coefficients are constants, invariant with temperature, density, or phase state.

📜 SIMILAR VOLUMES

Augmented back equation of state for pol

Augmented back equation of state for polar fluids

✍ M. J. Lee; K. C. Chao 📂 Article 📅 1988 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 756 KB

## Augmented BACK Equation of State for Polar Fluids The pressure of water is decoupled into a polar pressure and a nonpolar pressure, the latter being obtained from the BACK equation based on the size and nonpolar energy of the water molecule determined by Jorgensen and coworkers. The polar press

Further simplification of the augmented

Further simplification of the augmented back equation of state

✍ Chunlan Peng; Kwang-Chu Chao 📂 Article 📅 1991 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 374 KB

Backone family of equations of state: 2.

Backone family of equations of state: 2. Nonpolar and polar fluid mixtures

✍ Ulrike Weingerl; Martin Wendland; Johann Fischer; Andreas Müller; Jochen Winkelm 📂 Article 📅 2001 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 281 KB 👁 2 views

The VIM theory of molecular thermodynami

The VIM theory of molecular thermodynamics: Part II: Analytic equation of state of polar fluids

✍ A. H. Alem; G. A. Mansoori 📂 Article 📅 1984 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 543 KB

Extension of a quartic equation of state

Extension of a quartic equation of state to pure polar fluids

✍ Lian-yun Zang; Qing-li Zhu; Zhi Yun 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB 👁 1 views

Equation of state for fluid mixtures bas

Equation of state for fluid mixtures based on the principle of corresponding states with a two-fluid model: Application to fluid mixtures of water + ammonia

✍ Jun-ichi Suzuki; Masahiko Uematsu 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 96 KB 👁 3 views

## Abstract We propose an equation of state for fluid mixtures of water + ammonia which is expressed in Helmholtz free energy as a function of temperature, molar volume, and mole fraction. IAPWS Formulation 1995 for water and the equation of state by Tillner‐Roth and colleagues for ammonia should b