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AuCl 3 -Catalyzed Synthesis of Highly Substituted Furans from 2-(1-Alkynyl)-2-alken-1-ones

โœ Scribed by Yao, Tuanli; Zhang, Xiaoxia; Larock, Richard C.


Book ID
120077914
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
57 KB
Volume
126
Category
Article
ISSN
0002-7863

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On the mechanism of AuCl3-catalyzed synt
โœ Lizi Yang; Ran Fang; Yongcheng Wang ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› Elsevier ๐ŸŒ English โš– 540 KB

The mechanism of AuCl 3 -catalyzed synthesis of highly substituted furans from 2-(1-alkynyl)-2-alken-1-ones with nucleophiles have been investigated using density functional theory calculations done at the BHandHLYP/6-31G(d, p) (lanl2dz for Au) level of theory. Our calculations suggest that the firs