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Attractive Noncovalent Interactions in the Mechanism of Grubbs Second-Generation Ru Catalysts for Olefin Metathesis

โœ Scribed by Zhao, Yan; Truhlar, Donald G.

Book ID
121361036
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
137 KB
Volume
9
Category
Article
ISSN
1523-7060

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The efficient cross-metathesis of vinylsilanes carrying electron-withdrawing substituents with various olefins is described. High yields and selectivities were obtained when styrene, 1-hexene, and selective functional allyl derivatives were used as the olefins.