The coordination chemistry of Ln(hfpd) 3 (hfpd=1,1,1,5,5,5-hexafluoropentane-2,4-dionate) with phen and bpy depends on the size of the Ln 3 + ion and on the used solvent. The complexes [Er(hfpd) 3 (phen)] ( 7) and [Er(hfpd) 3 (bpy)] ( 14) were obtained from the synthesis of Er(CF 3 SO 3 ) 3 with Hhf
Attenuation of the luminescence of europium and samarium by impurity lanthanide ions in complexes with tenoyltrifluoroace tone and 1,10-phenanthroline
✍ Scribed by L. I. Kononenko; N. S. Poluéktov; R. A. Vitkun
- Publisher
- Springer US
- Year
- 1972
- Tongue
- English
- Weight
- 294 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0021-9037
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## Abstract Complexation of the lanthanides Eu^3+^, Gd^3+^, and Tb^3+^ with 1,4,7,10‐tetrakis(carboxymethyl)‐1,4,7,10‐tetraazacyclododecane (dota) has been studied in solution by using potentiometry, luminescence spectrometry, and EXAFS. Three series of successive complexes were characterized by at