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Attempting to grade phase transfer catalysts

✍ Scribed by R. C. Srivastava; R. Sahney; S. Upadhyay; R. L. Gupta

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
60 KB
Volume
12
Category
Article
ISSN
0894-3230

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✦ Synopsis

Electrical potential oscillations across liquid-liquid interfaces in phase transfer catalytic systems were studied. The possibility of using the amplitudes of these oscillations as a criterion for grading the catalysts in order of their efficacies for a reaction was suggested. Gradation in the efficacies of the catalysts derived on the basis of the gradation in the amplitudes in the reactions of nucleophilic nature was shown to be in agreement with the gradation in the partition coefficients of the nucleophiles in the presence of the phase transfer catalysts.

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