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Attempted reformatskii reaction of benzonitrile, 1,4-diketo-3,6-diphenylpyrrolo[3,4-C]pyrrole. A lactam analogue of pentalene.

✍ Scribed by Donald G. Farnum; Goverdhan Mehta; George G.I. Moore; Frederick P. Siegal

Book ID: 104244317
Publisher: Elsevier Science
Year: 1974
Tongue: French
Weight: 185 KB
Volume: 15
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93202-2

No coin nor oath required. For personal study only.

✦ Synopsis

Some time ago we became interested in the synthesis of derivatives of Z-azetlnone (1). a lactam analogue of the "antiaromatic" hydrocarbon, cyclobutadiene.

It seemed possible that a modification of the Reformatskii reaction, already used for the synthesis of Z-azetidinones, or g-lactams,

1 might yield Z-azetinones as well , as shown in equations ( ) and ( ).

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