✦ LIBER ✦

Attachment of the anthramycin acrylamide side chain by the palladium catalyzed coupling reaction of a vinyl triflate

✍ Scribed by Michael R. Peña; J.K. Stille

Book ID: 104228211
Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 188 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96916-8

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✦ Synopsis

Conversion of the 2-keto group in the pyrrolo ring of pyrrolo(l,4)benzodiazepines to the vinyl triflate takes place regiospecifically to yield the enamine.

The triflate undergoes palladium catalyzed coupling reactions to attach the acrylamide side chain.

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