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Attached proton test for carbon-13 NMR

✍ Scribed by Steven L Patt; James N Shoolery


Book ID
103186421
Publisher
Elsevier Science
Year
1982
Weight
224 KB
Volume
46
Category
Article
ISSN
0022-2364

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We have developed an extension of the APT 13C NMR experiment which differentiates tetracoordinate methine carbons and hexacoordinate 2-carboranyl carbons in complex organic molecules bearing o-carboranyl functionalities, as well as discriminating between pairs of carbons such as methylenes and termi

Residually coupled attached proton test
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Attached proton test (APT) spectra acquired with residual coupling (termed RECAPT) can be advantageous in assigning "C NMR spectra of complex natural products. RECAPT was applied to the analysis of the =C NMR spectra of two terpene marine natural products to iUustrate its advantages over APT in situ