ATRP Synthesis of Oligofluorene-Based Liquid Crystalline Conjugated Block Copolymers
✍ Scribed by Yu, Xin-Fei; Lu, Su; Ye, Chun; Li, Tingcheng; Liu, Tianxi; Liu, Shaoyong; Fan, Quli; Chen, Er-Qiang; Huang, Wei
- Book ID
- 126141843
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 275 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0024-9297
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## Abstract A series of smectic C^\*^ liquid‐crystalline (LC) block copolymers were successfully synthesized via the living anionic polymerization of polystyrene with optically active methacrylate monomers containing (__S__)‐2‐methylbutyl 4‐(4‐hydroxyphenylcarbonyloxy)‐biphenyl‐4′‐carboxylate mesog
Liquid crystalline (LC) block copolymers comprising polystyrene and LC polyester blocks were obtained by a three-step procedure. In a first step, hydroxyl-terminated oligoesters were obtained by polycondensation reaction of methylhydroquinone and 4,4'-dicarboxy-l,10dibenzoyloxydecane in pyridine sol