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Atropisomerism in (±)-7-methyl- and -phenyl-substituted dinaphtho[2,1-b;1′,2′-d]phospholes and dinaphth[2,1-b;1′,2′-d]arsoles

✍ Scribed by Andrew A. Watson; Anthony C. Willis; S.Bruce Wild

Book ID: 107812407
Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 699 KB
Volume: 445
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(93)80189-i

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## Abstract Novel 7‐phosphanorbornene derivatives, such as **4, 5, 10**, and **11** were synthesized utilizing 1‐phenyl‐2‐methyl‐2,5‐dihydro‐1H‐phosphole oxide (**1**) and 1‐cyclohexyl‐3‐methyl‐2,5‐dihydro‐1H‐phosphole oxide (**7**) as the starting materials. Products **4** and **10** were prepared