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Atomic and magnetic structures, phase separation, and unconventional superexchange interactions in Sr2GaMnO5+x (0<x<0.5) and Sr2GaMn(O,F)6

✍ Scribed by V Pomjakushin; D Sheptyakov; P Fischer; A Balagurov; A Abakumov; M Alekseeva; M Rozova; E Antipov


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
246 KB
Volume
350
Category
Article
ISSN
0921-4526

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New oxides of general formula Sr 2 Ru 2Àx Co x O 6Àd (0.5pxp1.5) have been synthesized as polycrystalline materials and characterized structurally by X-ray diffraction. For 0.5pxo0.67 the orthorhombic, Pnma, perovskite structure of the end member, SrRuO 3 , is found. At x ¼ 0.67 a phase separation i