Atom Transfer Radical Polymerization of Methyl Methacrylate in Fluoroalcohol: Simultaneous Control of Molecular Weight and Tacticity
β Scribed by Miura, Yutaka; Satoh, Toshifumi; Narumi, Atsushi; Nishizawa, Osamu; Okamoto, Yoshio; Kakuchi, Toyoji
- Book ID
- 127272495
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 72 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0024-9297
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## Abstract A highly soluble thymineβbased compound (1βoctyl thymine), having an array of hydrogen bonding sites with an ADA sequence (A and D: proton acceptor and donor sites, respectively), was used to mediate the stereospecific radical polymerization of an acrylamide monomer [__N__β(6βacetamidop
## Abstract The reverse atom transfer radical polymerization of methyl methacrylate was investigated in different solvents: xylene, __N,N__βdimethylformamide, and pyridine. The polymerizations were uncontrolled, using 2,2β²βbipyridine as a ligand in xylene and pyridine because the catalyst (CuBr~2~/