Atom transfer radical polymerization of hydrophilic monomers and its applications
✍ Scribed by He, Weiwei; Jiang, Hongjuan; Zhang, Lifen; Cheng, Zhenping; Zhu, Xiulin
- Book ID
- 120334553
- Publisher
- The Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 676 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1759-9954
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## Abstract **Summary:** A detailed investigation of the polymerization of glycidyl methacrylate (GMA), an epoxy‐functional monomer, by atom transfer radical polymerization (ATRP) was performed. Homopolymers were prepared at relatively low temperatures using ethyl 2‐bromoisobutyrate (EBrIB) as the
## Abstract A new copper catalyst containing chlorine and a photo‐labile diethylthiocarbamoylthiyl group was successfully employed in the reverse ATRP of methyl methacrylate (MMA). The polymeric chains were end‐capped with S~2~CNEt~2~, due to pseudo‐halogen atom‐transfer reaction between active and