Atom Transfer Radical Polymerization of 4-Vinylpyridine
✍ Scribed by Xia, Jianhui; Zhang, Xuan; Matyjaszewski, Krzysztof
- Book ID
- 115503470
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 95 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0024-9297
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## Abstract 2,2,6,6‐Tetramethylpiperidine‐__N__‐oxyl (TEMPO)‐mediated free radical polymerization of 4‐vinylpyridine is found to proceed in a “controlled” manner. A linear increase of molecular weight along with an increase in conversion occurs at varying temperatures. Polymerization of styrene wit
## Abstract Living atom transfer radical polymerization (ATRP) of 4‐acetoxystyrene (1), a protected 4‐vinylphenol, leading to poly(4‐acetoxystyrene) with well‐defined molecular weight and narrow molecular weight distribution was carried out in bulk with α,α′‐dibromoxylene(2)/CuBr/2,2‐bipyridine(bpy