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Atom Transfer Radical Polymerization of 2-Hydroxyethyl Methacrylate

✍ Scribed by Beers, Kathryn L.; Boo, Sohyun; Gaynor, Scott G.; Matyjaszewski, Krzysztof


Book ID
115454088
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
110 KB
Volume
32
Category
Article
ISSN
0024-9297

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The application of atom transfer radical polymerization (ATRP) to the homopolymerization of 2-hydroxyethyl acrylate, a functional monomer, is reported. The polymerizations exhibit first-order kinetics, and molecular weights increase linearly with conversion. Polydispersities remain low throughout th

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## Abstract Block copolymerization of 2‐(__N__,__N__‐dimethylamino)ethyl methacrylate (DMAEMA) with 2‐hydroxyethyl methacrylate (HEMA) via atom transfer radical polymerization (ATRP) was studied in methanol using a macroinitiator method and a β€œone‐pot” sequential addition method. The polymerization