Atmospheric chemistry: rate constants of the gas-phase reactions between haloalkanes of environmental interest and hydroxyl radicals
โ Scribed by C. Chiorboli; R. Piazza; M.L. Tosato; V. Carassiti
- Book ID
- 113138585
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 539 KB
- Volume
- 125
- Category
- Article
- ISSN
- 0010-8545
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๐ SIMILAR VOLUMES
Rate constants for the reactions of C1 atoms and OH radicals with haloalkanes were measured using the relative rate technique. From these values the atmospheric lifetimes of the organics with respect to C1 atoms and OH radicals were calculated. C1 atoms were produced by the photolysis of chlorine ga
The relative rate technique has been used to measure the hydroxyl radical (OH) reaction rate constant of hexamethyldisiloxane (MM, (CH 3 ) 3 Si -O -Si(CH 3 ) 3 ), octamethyltrisiloxane (MDM, (CH 3 ) 3 Si -O -Si(CH 3 ) 2 -O -Si(CH 3 ) 3 ), and decamethyltetrasiloxane (MD 2 M, (CH 3 ) 3 Si -O -Si(CH 3
Rate constants for three dimethylbenzaldehydes and two trimethylphenols have been determined for the OH reactions at and atmospheric pressure using a relative rate method. The OH reaction rate constants were placed on an absolute basis using the literature rate constant for 1,2,4-trimethylbenzene of