Asymmetry effects in atom-molecule collisions II
β Scribed by J. Reuss
- Publisher
- Elsevier Science
- Year
- 1964
- Weight
- 290 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0031-8914
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π SIMILAR VOLUMES
Classical trajectories are calculated on model surfaces designed to reproduce the reactive-unreactive bands found with the SShlK and Yates-Lester surfaces for the H + Hz system cmd other A f BC systems. The model surfaces are based on a rectiIinear reaction path, with a constant period of vibration,
Ther;ire ofconverpenceof~c~redcrosssectlollso uly~ CE)~shownto =xry sennti~elywith theenergyanddetenorates markedly when an mterfermg state (""-1") becomes energetically open.
lop-quadrupo!e effects are investigated via numerikl calculations of capture cross sections and computer-plotter : studies of ion trajectories in the quadrupole field. Capture cross sections are roughly equal to Langevin values for low rotatiox& temperatures; a large fraction of mult.iple reflection