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Asymmetric Total Synthesis of the Gastroprotective Microbial Agent AI-77-B.

✍ Scribed by Arun K. Ghosh; Alexander Bischoff; John Cappiello

Publisher: John Wiley and Sons
Year: 2003
Weight: 7 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200324202

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Diazobenzofluorene natural products are a family of structurally complex molecules with a tetracyclic (ABCD) framework bearing a diazo moiety, a functionality rarely found in nature (Scheme 1). Members of this family differ in the levels of functionalization of the cyclohexene moiety (D ring). Kina