Asymmetric Total Synthesis of (−)-Alkaloid 223A and Its 6-Epimer
✍ Scribed by Pu, Xiaotao; Ma, Dawei
- Book ID
- 117996364
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 142 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0022-3263
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Total Synthesis of the Cyclopeptide Alkaloid Sanjoinine G1 and Its C-11 Epimer. -An efficient new synthesis (18 steps, 6.6% overall yield) of sanjoinine G1 (VIII) is reported. The key steps in this synthesis are the formation of the alkyl-aryl ether linkage via an S N Ar reaction of amino alcohol (
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