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Asymmetric Synthesis of γ-Butyrolactones by Enantioselective Hydrogenation of Butenolides.

✍ Scribed by Paulo Marcos Donate; Daniel Frederico; Rosangela da Silva; Mauricio Gomes Constantino; Gino Del Ponte; Pierina Sueli Bonatto


Publisher
John Wiley and Sons
Year
2004
Weight
104 KB
Volume
35
Category
Article
ISSN
0931-7597

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Enantioselective Hydrogenation of β-Keto Sulfones with Chiral Ru(II)-Catalysts: Synthesis of Enantiomerically Pure Butenolides and γ-Butyrolactones. -A highly enantioselective synthesis of chiral β-hydroxy sulfones (II), (VII) and (XII) is presented involving a novel ruthenium-catalyzed hydrogenati