𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Asymmetric synthesis of β-substituted α-amino acids via a chiral nlii complex of dehydroalanine

✍ Scribed by Yuri N. Belokon'; Ashot S. Sagyan; Silva M. Djamgaryan; Vladimir I. Bakhmutov; Vasili M. Belikov

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
778 KB
Volume
44
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

✦ Synopsis

An efficient approach to thr asymmetric synthesis of ~substituted (Sines ie descrtbed.

Yv. N Buoros' CI al.

📜 SIMILAR VOLUMES

Asymmetric synthesis of α-amino acids vi
Asymmetric synthesis of α-amino acids via chiral N-alkylidenesulfinamides
✍ Duy H. Hua; Nadege Lagneau; Hui Wang; Jinshan Chen 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 226 KB

## SR)-(-)-N-[1-(Triethoxymethyl)ethylidene]-p-toluenesulfinamide (2) was synthesized from the addition reaction of triethoxyacetonitrile with MeLi followed by (+)-(R)-d-menthyl p-toluenesulfinate (1R). Sulfinimine 2 underwent complete stereoselective reduction with 9-BBN and addition reaction wit