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Asymmetric Synthesis of α-Amino Acids Based on Carbon Radical Addition to Glyoxylic Oxime Ether

✍ Scribed by Miyabe, Hideto; Ushiro, Chikage; Ueda, Masafumi; Yamakawa, Kumiko; Naito, Takeaki

Book ID: 127312481
Publisher: American Chemical Society
Year: 2000
Tongue: English
Weight: 131 KB
Volume: 65
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo991353n

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📜 SIMILAR VOLUMES

ChemInform Abstract: Asymmetric Synthesi

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Alkyl radical addition to glyoxylic oxime ether and hydrazone in aqueous media was studied using zinc dust as a radical initiator. The zinc-mediated radical reaction of the hydrazone bearing a chiral camphorsultam provided the corresponding alkylated products with good diastereoselectivities, which