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Asymmetric synthesis of (-)-quinocarcin

✍ Scribed by Garner, Philip; Ho, Wen Bin; Shin, Hunwoo


Book ID
115513262
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
293 KB
Volume
114
Category
Article
ISSN
0002-7863

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Stereoselective synthesis of an enantiomeric pair of the ABC-ring system of quinocarcin(l), a notable antitumor antibiotic, could be achieved in Z-95%ee by utilizing each enantiomer of 4-@benzyl-2,3-@isopropylidene-threose as a chiral auxiliary and featuring novel diastereoselective reduction of the

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