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Asymmetric Synthesis of Panaxydol (I) and Its Stereoisomers.

✍ Scribed by Hsi-Jung Yu; Chang-Ming Sun; Chien-Chih Chen; Tsao-Chin Wu; Chia-Ling Wei; Chien-Chang Shen


Publisher
John Wiley and Sons
Year
2004
Weight
54 KB
Volume
35
Category
Article
ISSN
0931-7597

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Monatin and Its Stereoisomers: Chemoenzy
✍ Angela Bassoli; Gigliola Borgonovo; Gilberto Busnelli; Gabriella Morini; Michael πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 139 KB

## Abstract The sweet natural compound monatin **1** has two stereogenic centres and the (2__S__,4__S__) absolute configuration has been attributed to the natural isomer. We obtained all four stereoisomers as pure compounds by a six‐step synthetic sequence. The stereogenic centre at C‐4 was introdu