✦ LIBER ✦
Asymmetric synthesis of optically pure α-methyl-β,γ-unsaturated ketones via triethylaluminum-mediated stereospecific pinacol rearrangement of alkenyl groups
✍ Scribed by Keisuke Suzuki; Eiji Katayama; Gen-ichi Tsuchihashi
- Book ID
- 104241301
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 255 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
OpticalZy pure a-methyZ-@,y-unsaturated ketones are synthesized by the Et3Al-mediated pinacoZ-type rearrangement where alkenyl groups migrate stereospecificaZ2y with complete retention of the oZefin-geometry.