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Asymmetric synthesis of naturally occurring nonenolide xyolide through cross metathesis and macrolactonization reaction

โœ Scribed by Rej, Rohan Kalyan; Jana, Anuvab; Nanda, Samik


Book ID
121810363
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
496 KB
Volume
70
Category
Article
ISSN
0040-4020

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## Abstract The utility of the readily available asymmetric 1,3โ€dioxane template in intramolecular Dielsโ€“Alder reactions is reported. The 1,3,9โ€decatrienoates substrates gave predominantly the __endo__โ€boat products, with minor amounts of the __exo__โ€boat isomer. Various substitutions (14 examples)