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Asymmetric Synthesis of Functionalized 1,3-Diphosphines via Chiral Palladium Complex Promoted Hydrophosphination of Activated Olefins

✍ Scribed by Yuan, Mingjun; Zhang, Na; Pullarkat, Sumod A.; Li, Yongxin; Liu, Fengli; Pham, Phuong-Tu; Leung, Pak-Hing


Book ID
127313097
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
971 KB
Volume
49
Category
Article
ISSN
0020-1669

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Asymmetric hydrosilylation of olefins ca
✍ Tamio Hayashi; Kohei Tamao; Yoshio Katsuro; Ichiro Nakae; Makoto Kumada πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 French βš– 223 KB

swmnary : Optically active norbornyl and l-phenylethyl alcohols and bromides were obtained, res- pectively, from norbornyl-and l-phenylethylpentafluorosilicates which were prepared by asymmetric hydrosilylation of norbornene and styrene with trichlorosilane catalyzed by a chiral ferrocenylphosphine-